Fundamentals of Absorption Refrigeration Cycle


Absorption refrigeration  is an established technology that uses low-quality heat (e.g., hot water or low-pressure exhaust gas) rather than electric power to drive the cooling cycle.

The vapor absorption refrigeration system comprises of all the processes in the vapor compression refrigeration system like compression, condensation, expansion and evaporation. In the vapor absorption system the refrigerant used is ammonia, water or lithium bromide. The refrigerant gets condensed in the condenser and it gets evaporated in the evaporator. The refrigerant produces cooling effect in the evaporator and releases the heat to the atmosphere via the condenser.

The major difference between the two systems is the method of the suction and compression of the refrigerant in the refrigeration cycle. In the vapor compression system, the compressor sucks the refrigerant from evaporator and compresses it to the high pressure. The compressor also enables the flow of the refrigerant through the whole refrigeration cycle. In the vapor absorption cycle, the process of suction and compression are carried out by two different devices called as the absorber and the generator.

Refrigerant

refrigerant is a substance or mixture, usually a fluid, used in a heat pump and refrigeration cycle. In most cycles it undergoes phase transitions from a liquid to a gas and back again.

Absorbent

The absorbent enables the flow of the refrigerant from the absorber to the generator by absorbing it. 

 Absorber

The absorber is a sort of vessel consisting of water that acts as the absorbent, and the previous absorbed refrigerant. Thus the absorber consists of the weak solution of the refrigerant (ammonia in this case) and absorbent (water in this case).

Generator:

Heat is supplied to the refrigerant water and absorbent lithium bromide solution in the generator from the steam or hot water. The water becomes vaporized and moves to the condenser, where it gets cooled.

Condenser

condenser unit used in central air conditioning systems typically has a heat exchanger section to cool down and condense incoming refrigerant vapor into liquid.

Refrigerant control

Refrigerant flow control is used to fine-tune the temperature in refrigerant devices by maintaining an optimal flow of refrigerant into its evaporator.

Concentrated Solution:

A Solution with a large amount/concentration of absorbant and only small amount of refrigerant is known as concentrated solution and also known as weak solution.

Dilute Solution:

An absorbent solution dilute by large amount of dissolved refrigerant is known as dilute solution.it is also known as strong solution.

Heat of condensation:

Heat evolved when a vapor changes to a liquid specifically.

Heat of dilution 

Definition is - the heat evolved per mole of solute when a solution is greatly diluted.

Evaporator:

 Water as the refrigerant enters the evaporator at a very low pressure and temperature. Since very low pressure is maintained inside the evaporator the water exists in a partial liquid state and partial vapor state. This water refrigerant absorbs the heat from the substance to be chilled and gets fully evaporated. It then enters the absorber.

 Pump

When the absorbent absorbs the refrigerant strong solution of refrigerant-absorbent (water-Lithium bromide) is formed. This solution is pumped by the pump at high pressure to the generator.


 Heat Exchangers:

Two heat exchangers are provided to internally exchange heat from the higher tempera­ture fluid to the lower temperature fluid so that one is cooled and the other is heated.

Special Features of Water-Lithium Bromide Solution

Here are some special features of the water and lithium bromide in an absorption refrigeration system:
1) Lithium bromide has great affinity for water vapor, however, when the water-lithium bromide solution is formed, they are not completely soluble with each other under all the operating conditions of the absorption refrigeration system. Because of this, the designer must take care that such conditions would not be created where crystallization and precipitation of the lithium bromide would occur.

2) The water used as the refrigerant in the absorption refrigeration system means the operating pressures in the condenser and the evaporator must be very low. Even the difference of pressure between the condenser and the evaporator must be very low. This can be achieved even without installing the expansion valve in the system, since the drop in pressure occurs due to friction in the refrigeration piping and in the spray nozzles.

3) The capacity of any absorption refrigeration system depends on the ability of the absorbent to absorb the refrigerant, which in turn depends on the concentration of the absorbent. To increase the capacity of the system, the concentration of absorbent should be increased, which would enable absorption of more refrigerant. Some of the most common methods used to change the concentration of the absorbent are: controlling the flow of the steam or hot water to the generator, controlling the flow of water used for condensing in the condenser, and re-concentrating the absorbent leaving the generator and entering the absorber.


In a water-lithium bromide vapor absorption refrigeration system, water is used as the refrigerant while lithium bromide (Li Br) is used as the absorbent. In the absorber, the lithium bromide absorbs the water refrigerant, creating a solution of water and lithium bromide. This solution is pumped by the pump to the generator where the solution is heated. The water refrigerant gets vaporized and moves to the condenser where it is cooled while the lithium bromide flows back to the absorber where it further absorbs water coming from the evaporator.
The water-lithium bromide vapor absorption system is used in a number of air conditioning applications. This system is useful for applications where the temperature required is more than 32 degree F.


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